CCHF Research | Catalyst Controlled Site Selectivity
Led by Justin Du Bois and Cora MacBeth
The design and synthesis of organometallic complexes with ligand architectures effective at guiding the substrate to the active site through steric and electronic interactions.
Related Publications:
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01/2019
Synthesis and Catalytic Properties of Dirhodium Paddlewheel Complexes with Tethered, Axially Coordinating Thioether Ligands
RESEARCH
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01/2019
New chromium, molybdenum, and cobalt complexes of the chelating esp ligand
RESEARCH
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12/2018
Desymmetrization of cyclohexanes by site- and stereoselective C–H functionalization
RESEARCH
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09/2018
Intermolecular Allylic C−H Etherification of Internal Olefins
RESEARCH
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09/2018
Comparison of Reactivity and Enantioselectivity between Chiral Bimetallic Catalysts: Bismuth–Rhodium- and Dirhodium-Catalyzed Carbene Chemistry
RESEARCH
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08/2018
Design of catalysts for site-selective and enantioselective functionalization of non-activated primary C–H bonds
RESEARCH
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01/2018
Site-Selective Carbene-Induced C–H Functionalization Catalyzed by Dirhodium Tetrakis(triaryl cyclopropanecarboxylate) Complexes
RESEARCH
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11/2017
Site-selective and stereoselective functionalization of non-activated tertiary C–H bonds
RESEARCH
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11/2017
Rhodium Complexes of 2,6-Bis(dialkylphosphinomethyl)pyridines: Improved C–H Activation, Expanded Reaction Scope, and Catalytic Direct Arylation
RESEARCH
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06/2017
Ruthenium-Catalyzed C–H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives
RESEARCH
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06/2017
Synthesis of D/A-Substituted Diazo Compounds in Flow and Their Application in Enantioselective Dirhodium-Catalyzed Cyclopropanation and C–H Functionalization
RESEARCH
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10/2016
Catalyst-Controlled and Tunable, Chemoselective Silver-Catalyzed Intermolecular Nitrene Transfer: Experimental and Computational Studies
RESEARCH
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09/2016
Ligand-accelerated enantioselective methylene C(sp3)–H bond activation
RESEARCH
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05/2016
Site Selective and Stereoselective Functionalization of Unactivated C–H Bonds
RESEARCH
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05/2016
The first bismuth(II)–rhodium(II) oxypyridinate paddlewheel complexes: Synthesis and structural characterization
RESEARCH
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02/2016
Iridium(III)-bis(imidazolinyl)phenyl catalysts for enantioselective C–H functionalization with ethyl diazoacetate
RESEARCH
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01/2016
Rh2(II,III) Catalysts with Chelating Carboxylate and Carboxamidate Supports: Electronic Structure and Nitrene Transfer Reactivity
RESEARCH
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11/2015
Expanding the family of heterobimetallic Bi–Rh paddlewheel carboxylate complexes via equatorial carboxylate exchange
RESEARCH
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12/2015
Comparative Study of the Limitations and Challenges in Atom-Transfer C–H Oxidations
RESEARCH
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06/2015
Ir-Catalyzed enantioselective group transfer reactions
RESEARCH
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07/2014
Speciation and decomposition pathways of ruthenium catalysts used for selective C–H hydroxylation
RESEARCH
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06/2014
Role of Sterically Demanding Chiral Dirhodium Catalysts in Site-Selective C–H Functionalization of Activated Primary C–H Bonds
RESEARCH
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11/2013
Silica-Immobilized Chiral Dirhodium(II) Catalyst for Enantioselective Carbenoid Reactions
RESEARCH
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09/2013
Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex
RESEARCH
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09/2012
Capturing fleeting intermediates in a catalytic C–H amination reaction cycle
RESEARCH
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11/2011
Synthesis of Ruthenium(II)-2,6-Bisiminopyridyl Complexes for C-H Amination of Sulfamate Esters
RESEARCH
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11/2011
D2-Symmetric Dirhodium Catalyst Derived from a 1,2,2-triarylcyclopropane carboxylate Ligand: Design, Synthesis and Application
RESEARCH
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10/2011
A Diruthenium Catalyst for Selective, Intramolecular Allylic C-H Amination
RESEARCH
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01/2010
Solvent-free catalytic enantioselective C–C bond forming reactions with very high catalyst turnover numbers
RESEARCH